BIOMAT Database Logo BIOMAT Database Logo

Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents. 2016

Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST, UK. cc111@st-andrews.ac.uk.

Homo- and heteroleptic bis-NHC copper(I) complexes have been efficiently used as carbene transfer reagents to Au and Pd. The simple and straightforward procedure allows for the synthesis of well-known gold complexes as well as novel cationic bis-NHC Pd(II) species.

UI MeSH Term Description Entries

Related Publications

Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents.
October 2010, Chemical communications (Cambridge, England),
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
NHC-manganese(i) complexes as carbene transfer agents.
September 2009, Dalton transactions (Cambridge, England : 2003),
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
Straightforward synthesis of [Cu(NHC)(alkynyl)] and [Cu(NHC)(thiolato)] complexes (NHC = N-heterocyclic carbene).
December 2021, Dalton transactions (Cambridge, England : 2003),
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
Copper(i)-NHC complexes as NHC transfer agents.
January 2017, Dalton transactions (Cambridge, England : 2003),
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
Heteroleptic dirhodium(II,II) paddlewheel complexes as carbene transfer catalysts.
October 2021, Organic & biomolecular chemistry,
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
"Click" synthesis of heteroleptic tris-cyclometalated iridium(III) complexes: Cu(I) triazolide intermediates as transmetalating reagents.
August 2011, Inorganic chemistry,
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes.
November 2013, Chemical communications (Cambridge, England),
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
Heteroleptic Cu(I) bis-diimine complexes as sensitizers in dye-sensitized solar cells (DSSCs): on some factors affecting intramolecular charge transfer.
July 2022, Physical chemistry chemical physics : PCCP,
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
Emission properties and Cu(i)-Cu(i) interaction in 2-coordinate dicopper(i)-bis(N-heterocyclic)carbene complexes.
July 2016, Dalton transactions (Cambridge, England : 2003),
Orlando Santoro, and Faïma Lazreg, and David B Cordes, and Alexandra M Z Slawin, and Catherine S J Cazin
Homoleptic and heteroleptic Au(I) complexes containing the new [Co5C(CO)12](-) cluster as ligand.
July 2014, Dalton transactions (Cambridge, England : 2003),
Copied contents to your clipboard!