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When CMRP met alkyl vinyl ketone: visible light induced living radical polymerization (LRP) of ethyl vinyl ketone (EVK). 2016
Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare EarthMaterials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China. fuxf@pku.edu.cn.
Photo responsive polyethyl vinyl ketone (PEVK) and various block copolymers were prepared through the visible light induced cobalt mediated radical polymerization (CMRP) process. The first order kinetics and linear increase in molecular weight with conversion demonstrated a well-behaved system. Chain extension experiments showed the retention of the living end of PEVK.
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