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Mono- and Dihydroxylated Symmetrical Octamethylcucurbiturils and Allylated Derivatives. 2016
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University , Guiyang, Guizhou 550025, China.
Mono- and dihydroxylated symmetrical octamethylcucurbit[6]urils {(OH)OMeQ[6] and (OH)2OMeQ[6]} were prepared using a photochemical method to introduce limited alcohol group(s) directly to the parent symmetrical octamethylcucurbit[6]uril (OMeQ[6]), and the resulting compounds were verified by 1H NMR, Xevo Q-TOF MS, and X-ray crystallography. Further chemical modification of mono- and dihydroxylated OMeQ[6] was also performed.
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