Viscoelastic properties of elastomeric impression materials: polysulphide, silicone and polyether rubbers. 1978

L G Tolley, and R G Craig

Creep compliance measurements were shown to be effective in characterizing the elastic, retarded elastic, and viscous properties of polysulphide, silicone, and polyether impression materials. The test is particularly valuable in that the creep compliance was independent of load, allowing the mechanical properties to be represented by a single total creep compliance curve which can be used to determine the various creep components. The total recovered compliance was shown to be independent of time provided the polymerization had progressed sufficiently before testing was done. The retarded elastic and viscous compliances contributed proportionally to the total creep compliance and thus did not affect the rankings of materials. The viscous compliance of polysulphide A decreased enough after 1 h so that the creep compliance of A and D were not different. The creep compliance measurements showed that the polysulphide materials were the most viscoelastic followed by silicone and polyether impression materials. The polyether was the most nearly ideal elastic material but it had a flexibility comparable to heavy body polysulphide. Of particular interest was the observation that polyether with thinner in ratios up to 1 : 1 by length had no practical effect on the viscoelastic properties.

UI MeSH Term Description Entries
D011108 Polymers Compounds formed by the joining of smaller, usually repeating, units linked by covalent bonds. These compounds often form large macromolecules (e.g., BIOPOLYMERS; PLASTICS). Polymer
D003760 Dental Impression Materials Substances used to create an impression, or negative reproduction, of the teeth and dental arches. These materials include dental plasters and cements, metallic oxide pastes, silicone base materials, or elastomeric materials. Dental Impression Material,Impression Material, Dental,Impression Materials, Dental,Material, Dental Impression,Materials, Dental Impression
D004548 Elasticity Resistance and recovery from distortion of shape.
D004987 Ethers Organic compounds having two alkyl or aryl groups bonded to an oxygen atom, as in the formula R1–O–R2.
D012408 Rubber A high-molecular-weight polymeric elastomer derived from the milk juice (LATEX) of HEVEA brasiliensis and other trees and plants. It is a substance that can be stretched at room temperature to at least twice its original length and after releasing the stress, retract rapidly, and recover its original dimensions fully. Latex Rubber,Elastica,India Rubber,Natural Rubber,Plant Rubber,Vulcanite,Natural Rubbers,Plant Rubbers,Rubber, Natural,Rubber, Plant,Rubbers, Natural,Rubbers, Plant
D012826 Silicone Elastomers Polymers of silicone that are formed by crosslinking and treatment with amorphous silica to increase strength. They have properties similar to vulcanized natural rubber, in that they stretch under tension, retract rapidly, and fully recover to their original dimensions upon release. They are used in the encapsulation of surgical membranes and implants. Elastomers, Silicone,Rubber Silicone,Silicone Rubber,Elastosil,Microfil,SE-30,Elastosils,Microfils,SE 30,SE30,Silicone Elastomer
D013314 Stress, Mechanical A purely physical condition which exists within any material because of strain or deformation by external forces or by non-uniform thermal expansion; expressed quantitatively in units of force per unit area. Mechanical Stress,Mechanical Stresses,Stresses, Mechanical
D013440 Sulfides Chemical groups containing the covalent sulfur bonds -S-. The sulfur atom can be bound to inorganic or organic moieties. Sulfide,Thioether,Thioethers,Sulfur Ethers,Ethers, Sulfur
D014783 Viscosity The resistance that a gaseous or liquid system offers to flow when it is subjected to shear stress. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 6th ed) Viscosities

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