-transparent.png){kind=logo}
A 11-Steps Total Synthesis of Magellanine through a Gold(I)-Catalyzed Dehydro Diels-Alder Reaction. 2017
Center for Catalysis Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie-Curie, Ottawa, K1N 6N5, Canada.
We have developed an innovative strategy for the formation of angular carbocycles via a gold(I)-catalyzed dehydro Diels-Alder reaction. This transformation provides rapid access to a variety of complex angular cores in excellent diastereoselectivities and high yields. The usefulness of this AuI -catalyzed cycloaddition was further demonstrated by accomplishing a 11-steps total synthesis of (±)-magellanine.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
June 2018,
Organic letters,
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
June 2008,
Chemical reviews,
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
July 2000,
Organic letters,
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
October 2011,
Organic & biomolecular chemistry,
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
May 2022,
The Journal of organic chemistry,
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
August 2019,
Organic letters,
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
April 2021,
Organic letters,
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
May 2002,
Angewandte Chemie (International ed. in English),
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
January 2016,
Chemistry (Weinheim an der Bergstrasse, Germany),
Philippe McGee, and
Geneviève Bétournay, and
Francis Barabé, and
Louis Barriault
May 2022,
The Journal of organic chemistry,
