-transparent.png){kind=logo}
Diastereoselective Synthesis of Dibenzo[b,d]azepines by Pd(II)-Catalyzed [5 + 2] Annulation of o-Arylanilines with Dienes. 2017
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University , Xi'an 710127, China.
An efficient method for the construction of dibenzo[b,d]azepines containing two distinct stereogenic elements in a highly diastereoselective fashion is described. The key of the [5 + 2] reaction is to form a π-allylpalladium species through sequential C-H activation and regiospecific migratory insertion of the diene. This observation contrasts with the behavior of 1,2-alkenes that generally underwent direct alkenylation via β-hydride elimination.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
December 2015,
Angewandte Chemie (International ed. in English),
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
December 2021,
Chemical science,
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
March 2024,
Chemical communications (Cambridge, England),
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
July 2021,
The Journal of organic chemistry,
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
March 2003,
Organic letters,
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
December 2018,
Organic letters,
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
June 2010,
The Journal of organic chemistry,
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
July 2008,
Journal of the American Chemical Society,
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
April 2019,
Organic letters,
Lu Bai, and
Yan Wang, and
Yicong Ge, and
Jingjing Liu, and
Xinjun Luan
June 2007,
Organic letters,
