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Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework. 2017

Linfeng Liang, and Caiping Liu, and Feilong Jiang, and Qihui Chen, and Linjie Zhang, and Hui Xue, and Hai-Long Jiang, and Jinjie Qian, and Daqiang Yuan, and Maochun Hong
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.

Considering the rapid increase of CO2 emission, especially from power plants, there is a constant need for materials which can effectively eliminate post-combustion CO2 (the main component: CO2/N2 = 15/85). Here, we show the design and synthesis of a Cu(II) metal-organic framework (FJI-H14) with a high density of active sites, which displays unusual acid and base stability and high volumetric uptake (171 cm3 cm-3) of CO2 under ambient conditions (298 K, 1 atm), making it a potential adsorbing agent for post-combustion CO2. Moreover, CO2 from simulated post-combustion flue gas can be smoothly converted into corresponding cyclic carbonates by the FJI-H14 catalyst. Such high CO2 adsorption capacity and moderate catalytic activity may result from the synergistic effect of multiple active sites.

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