An iron-catalyzed hydroalkylation reaction of α,β-unsaturated ketones with ethers. 2017

Yun Lan, and Pei Fan, and Xiao-Wei Liu, and Fei-Fan Meng, and Tanveer Ahmad, and Yun-He Xu, and Teck-Peng Loh
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. xyh0709@ustc.edu.cn.

A general strategy for the hydroalkylation of vinyl ketones using ethers catalyzed by an iron catalyst is described. This catalytic method permits direct transformation of easily accessible and abundant precursors into highly substituted, structurally diverse and functionally concentrated products.

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