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Ni-catalyzed two-component reductive dicarbofunctionalization of alkenes via radical cyclization. 2018

Yulong Kuang, and Xuefeng Wang, and David Anthony, and Tianning Diao
Department, New York University, 100 Washington Square E., New York, NY 10003, USA. diao@nyu.edu.

A reductive dicarbofunctionalization reaction of alkenes has been developed and applied to the preparation of substituted carbo- and heterocycles. The reaction conditions avoid the use of air-sensitive organometallic reagents, and are compatible with a broad range of bromo-electrophiles and a wide variety of substituents to give cyclic products in excellent yields.

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