Total Synthesis of the Neoclerodane Diterpene Salvinorin A via an Intramolecular Diels-Alder Strategy. 2018

Yuzhou Wang, and Peter Metz
Fakultät Chemie und Lebensmittelchemie, Organische Chemie I , Technische Universität Dresden , Bergstrasse 66 , 01069 Dresden , Germany.

A concise total synthesis of the neoclerodane diterpene salvinorin A from 3-furaldehyde is reported using two highly diastereoselective intramolecular Diels-Alder reactions (IMDA) as the key transformations.

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