-transparent.png){kind=logo}
Rhodium-catalyzed C-H functionalization of heteroarenes using indoleBX hypervalent iodine reagents. 2018
Laboratory of Catalysis and Organic Synthesis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fedérale de Lausanne, EPFL SB ISIC LCSO, BCH 4306, 1015 Lausanne, Switzerland.
The C-H indolation of heteroarenes was realized using the benziodoxolone hypervalent iodine reagents indoleBXs. Functionalization of the C-H bond in bipyridinones and quinoline N-oxides catalyzed by a rhodium complex allowed to incorporate indole rings into aza-heteroaromatic compounds. These new transformations displayed complete regioselectivity for the C-6 position of bipyridinones and the C-8 position of quinoline N-oxides and tolerated a broad range of functionalities, such as halogens, ethers, or trifluoromethyl groups.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
August 2019,
The Journal of organic chemistry,
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
November 2017,
The Journal of organic chemistry,
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
March 2018,
Organic letters,
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
January 2016,
Chemistry (Weinheim an der Bergstrasse, Germany),
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
March 2018,
Organic letters,
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
July 2016,
Organic letters,
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
February 2023,
Organic letters,
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
December 2021,
Organic letters,
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
July 2019,
Organic & biomolecular chemistry,
Erwann Grenet, and
Ashis Das, and
Paola Caramenti, and
Jérôme Waser
March 2018,
Organic letters,
