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A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds. 2018
Claudia Lar, and
Adrian Woiczechowski-Pop, and
Attila Bende, and
Ioana Georgeta Grosu, and
Natalia Miklášová, and
Elena Bogdan, and
Niculina Daniela Hădade, and
Anamaria Terec, and
Ion Grosu
Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Department of Chemistry and SOOMCC, Cluj-Napoca, 11 Arany Janos str., 400028, Cluj-Napoca, Romania.
The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and molecular modelling investigations proved the formation of 1:1 host-guest assemblies between the investigated cryptand and some polynuclear aromatic hydrocarbons or their derivatives.
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