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[3 + 2] Cycloaddition of Nitrile Ylides with Diazonium Salts: Copper-Catalyzed One-Pot Synthesis of Fully Substituted 1,2,4-Triazoles. 2018
Huihuang Li, and
Xueli Wu, and
Weiwei Hao, and
Haiyan Li, and
Yanwei Zhao, and
Yaxiong Wang, and
Pengcheng Lian, and
Yonggao Zheng, and
Xiaoguang Bao, and
Xiaobing Wan
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science , Soochow University , Suzhou 215123 , People's Republic of China.
A novel [3 + 2] cycloaddition between nitrile ylides and diazonium salts was well-established. This copper-catalyzed three-component reaction was distinguished by mild conditions, ready availability, and operational simplicity, thus opening access to 1,2,4-triazoles with a diverse set of substitution patterns.
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