In order to improve the strength of polyvinyl alcohol (PVA)/xylan composite films and endow them with ultraviolet (UV) shielding ability, TiO₂-KH550 nanoparticles was synthesized and added into the PVA/xylan matrix. The TiO₂-KH550 nanoparticle dispersed well in the 0.04% sodium hexametaphosphate (SHMP) solution under ultrasonic and stirring treatments. Investigations on the properties of the films showed that TiO₂-KH550 had the positive impact on improving the strength, moisture, and oxygen barrier properties of the composite films. The maximum tensile strength (27.3 MPa), the minimum water vapor permeability (2.75 × 10-11 g·m-1·s-1·Pa-1), and oxygen permeability (4.013 cm³·m-2·24 h-1·0.1MPa-1) were obtained under the addition of 1.5% TiO₂-KH550. The tensile strength of TiO₂-KH550 reinforced composite film was increased by 70% than that of the pure PVA/xylan composite film, and the water vapor and oxygen permeability were decreased by 31% and 41%, respectively. Moreover, the UV transmittance of the film at the wavelength of 400 nm was almost zero when adding ≈1.5~2.5% (weight ratio, based on the total weight of PVA and xylan) of TiO₂-KH550, which indicated the PVA/xylan composite films were endowed with an excellent UV light shielding ability.