Studies on the properties and biodegradability of PVA/Trapa natans starch (N-st) composite films and PVA/N-st-g-poly (EMA) composite films. 2019

Kuljit Kaur, and Rajeev Jindal, and Mithu Maiti, and Shreya Mahajan
Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar 144011, Punjab, India.

The morphological modification of Trapa natans starch was done by grafting the methylmethacrylate (EMA) using ferrous ammonium sulphate‑potassium persulphate as a redox initiator. Different reaction parameters such as reaction temperature, time, monomer concentration, pH and solvent were optimized to get maximum graft yield (56%). The graft copolymers thus formed were characterized by Fourier transform infrared, scanning electron microscopy, X-ray diffraction and TGA/DTA/DTG techniques. PVA/starch (N-st) composite films and PVA/N-Starch-grafted-poly (EMA) composite films were prepared separately by using glycerol as a plasticizer. The effect and content of grafted starch on the mechanical properties, water uptake (%), and biodegradability of the composite films were observed. Elongation at break % of PVA/starch-grafted-poly (EMA) (1:1) increased up to 38.9% of pure PVA/N-starch composites (1:1). With further increase in the ratio of grafted starch from (50% to 70%) Elongation at break, % increased to a great extent. There was 223.14% increased in PVA/starch-grafted-poly (EMA) (3:7) as compared to pure PVA/N-starch (3:7) composite films. The Max stress increased up to 100% in PVA/N-starch-grafted-poly (EMA) (3:7) composite film of pure PVA/N-starch composite films (3:7). There were 41.63% decreases in water uptake in PVA/N-starch-grafted-poly (EMA) (3:7) composite films as compared to PVA/N-starch composite films.

UI MeSH Term Description Entries
D011142 Polyvinyl Alcohol A polymer prepared from polyvinyl acetates by replacement of the acetate groups with hydroxyl groups. It is used as a pharmaceutic aid and ophthalmic lubricant as well as in the manufacture of surface coatings artificial sponges, cosmetics, and other products. Liquifilm Tears,Polyviol,Alcohol, Polyvinyl,Tears, Liquifilm
D006863 Hydrogen-Ion Concentration The normality of a solution with respect to HYDROGEN ions; H+. It is related to acidity measurements in most cases by pH pH,Concentration, Hydrogen-Ion,Concentrations, Hydrogen-Ion,Hydrogen Ion Concentration,Hydrogen-Ion Concentrations
D001672 Biocompatible Materials Synthetic or natural materials, other than DRUGS, that are used to replace or repair any body TISSUES or bodily function. Biomaterials,Bioartificial Materials,Hemocompatible Materials,Bioartificial Material,Biocompatible Material,Biomaterial,Hemocompatible Material,Material, Bioartificial,Material, Biocompatible,Material, Hemocompatible
D012987 Soil The unconsolidated mineral or organic matter on the surface of the earth that serves as a natural medium for the growth of land plants. Peat,Humus,Soils
D012997 Solvents Liquids that dissolve other substances (solutes), generally solids, without any change in chemical composition, as, water containing sugar. (Grant & Hackh's Chemical Dictionary, 5th ed) Solvent
D013213 Starch Any of a group of polysaccharides of the general formula (C6-H10-O5)n, composed of a long-chain polymer of glucose in the form of amylose and amylopectin. It is the chief storage form of energy reserve (carbohydrates) in plants. Amylomaize Starch,Amylum,Cornstarch,Keoflo,Starch, Amylomaize
D013696 Temperature The property of objects that determines the direction of heat flow when they are placed in direct thermal contact. The temperature is the energy of microscopic motions (vibrational and translational) of the particles of atoms. Temperatures
D013818 Thermogravimetry Technique whereby the weight of a sample can be followed over a period of time while its temperature is being changed (usually increased at a constant rate). Thermogravimetries
D014867 Water A clear, odorless, tasteless liquid that is essential for most animal and plant life and is an excellent solvent for many substances. The chemical formula is hydrogen oxide (H2O). (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Hydrogen Oxide
D014961 X-Ray Diffraction The scattering of x-rays by matter, especially crystals, with accompanying variation in intensity due to interference effects. Analysis of the crystal structure of materials is performed by passing x-rays through them and registering the diffraction image of the rays (CRYSTALLOGRAPHY, X-RAY). (From McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Xray Diffraction,Diffraction, X-Ray,Diffraction, Xray,Diffractions, X-Ray,Diffractions, Xray,X Ray Diffraction,X-Ray Diffractions,Xray Diffractions

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