Biomaterial Database

Preparation of low shrinkage stress Bis-GMA free dental resin composites with a synthesized urethane dimethacrylate monomer. 2019

Shuzhen Luo, and Fang Liu, and Biao Yu, and Jingwei He

a College of Materials Science and Engineering, South China University of Technology , Guangzhou , China.

A new urethane dimethacrylate TMA was synthesized through a typical urethane reaction. TMA was used to replace 1,6-bis(methacryloxy-2-ethoxycarbonyl- amino)-2,4,4- trimethylhexane (UDMA) in UDMA based composite partially or totally to prepare TMA containing composites. Critical properties of TMA containing composites were investigated. 2,2-bis[4(2-hydroxy-3-methacryloy- propyloy)phenyl]propane (Bis-GMA) based and UDMA based composites were used as references. FT-IR and 1H-NMR confirmed the structure of TMA. All of experimental dental resin composites had the similar double bond conversion (p > 0.05). With a certain amount of TMA, TMA containing composites could have lower volumetric shrinkage (p < 0.05) and shrinkage stress (p < 0.05) than control groups. Water sorption, solubility, flexural strength and modulus of TMA containing composites were not worse than those of control groups. All of TMA containing composites and UDMA based composite had the same fracture toughness (p > 0.05), which was higher than that of Bis-GMA based composite (p < 0.05). TMA has potential as Bis-GMA substitute to prepare Bis-GMA free dental resin composites with low shrinkage stress.

UI	MeSH Term	Description	Entries
D008422	Materials Testing	The testing of materials and devices, especially those used for PROSTHESES AND IMPLANTS; SUTURES; TISSUE ADHESIVES; etc., for hardness, strength, durability, safety, efficacy, and biocompatibility.	Biocompatibility Testing,Biocompatible Materials Testing,Hemocompatibility Testing,Testing, Biocompatible Materials,Testing, Hemocompatible Materials,Hemocompatibility Testings,Hemocompatible Materials Testing,Materials Testing, Biocompatible,Materials Testing, Hemocompatible,Testing, Biocompatibility,Testing, Hemocompatibility,Testing, Materials,Testings, Biocompatibility
D008689	Methacrylates	Acrylic acids or acrylates which are substituted in the C-2 position with a methyl group.	Methacrylate
D011140	Polyurethanes	A group of thermoplastic or thermosetting polymers containing polyisocyanate. They are used as ELASTOMERS, as coatings, as fibers and as foams.	Polyisocyanates,Ostamer,Pellethane,Spandex,Ostamers,Pellethanes,Polyisocyanate,Polyurethane,Spandices
D012117	Resins, Synthetic	Polymers of high molecular weight which at some stage are capable of being molded and then harden to form useful components.	Dental Resins,Dental Resin,Resin, Dental,Resin, Synthetic,Resins, Dental,Synthetic Resin,Synthetic Resins
D003188	Composite Resins	Synthetic resins, containing an inert filler, that are widely used in dentistry.	Composite Resin,Resin, Composite,Resins, Composite
D000077298	Flexural Strength	The maximum MECHANICAL STRESS that a heterogeneous material, subject to a bending load or flexure, can withstand before fracturing.	Bend Strength,Flexural Properties,Flexural Resistance,Fracture Strength,Modulus of Rupture,Bend Strengths,Flexural Property,Flexural Resistances,Flexural Strengths,Fracture Strengths,Properties, Flexural,Property, Flexural,Resistance, Flexural,Resistances, Flexural,Rupture Modulus,Strength, Bend,Strength, Flexural,Strength, Fracture,Strengths, Bend,Strengths, Flexural,Strengths, Fracture
D000180	Acrylic Resins	Polymers of high molecular weight which are derived from acrylic acid, methacrylic acid or other related compounds and are capable of being molded and then hardened to form useful components.	Acrylic Resin,Resin, Acrylic,Resins, Acrylic
D012995	Solubility	The ability of a substance to be dissolved, i.e. to form a solution with another substance. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 6th ed)	Solubilities
D013329	Structure-Activity Relationship	The relationship between the chemical structure of a compound and its biological or pharmacological activity. Compounds are often classed together because they have structural characteristics in common including shape, size, stereochemical arrangement, and distribution of functional groups.	Relationship, Structure-Activity,Relationships, Structure-Activity,Structure Activity Relationship,Structure-Activity Relationships
D015394	Molecular Structure	The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds.	Structure, Molecular,Molecular Structures,Structures, Molecular