Defect structure of superconducting YBa2Cu3O7-delta. 1988

G Van Tendeloo, and S Amelinckx
Universiteit Antwerpen, R.U.C.A., Antwerp, Belgium.

The superconducting material Y1Ba2Cu3O7-delta has been investigated by electron microscopy. Special attention has been paid to the defects occurring in the material. Twinning on (110) or (110) planes is intrinsically related to the orthorhombicity, and when cooled slowly the twin bands are pseudoperiodic with an average width of approximately 50 nm. The orthorhombic-tetragonal transition is reversible and diffusion controlled. Under particular conditions and in slightly reduced material a 2a0 x b0 superstructure resulting from vacancy ordering is formed. When kept in air under powder form the material seems to be unstable. Planar defects along (001) accompany the degeneration of the material.

UI MeSH Term Description Entries
D008854 Microscopy, Electron Microscopy using an electron beam, instead of light, to visualize the sample, thereby allowing much greater magnification. The interactions of ELECTRONS with specimens are used to provide information about the fine structure of that specimen. In TRANSMISSION ELECTRON MICROSCOPY the reactions of the electrons that are transmitted through the specimen are imaged. In SCANNING ELECTRON MICROSCOPY an electron beam falls at a non-normal angle on the specimen and the image is derived from the reactions occurring above the plane of the specimen. Electron Microscopy
D003461 Crystallography The branch of science that deals with the geometric description of crystals and their internal arrangement. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Crystallographies
D004553 Electric Conductivity The ability of a substrate to allow the passage of ELECTRONS. Electrical Conductivity,Conductivity, Electric,Conductivity, Electrical

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