Improved Efficiency of Perovskite Solar Cells by the Interfacial Modification of the Active Layer. 2019

Zhen Lu, and Shangzhi Wang, and Huijun Liu, and Feng Feng, and Wenhua Li
College of Chemistry and Environmental Engineering, ShanXi DaTong University, Datong 037009, China. luzhen0313@aliyun.com.

As the most promising material for thin-film solar cells nowadays, perovskite shine for its unique optical and electronic properties. Perovskite-based solar cells have already been demonstrated with high efficiencies. However, it is still very challenging to optimize the morphology of perovskite film. In this paper we proposed a smooth and continuous perovskite active layer by treating the poly (3, 4-ethylenedioxythiophene): poly (styrenesulphonate) (PEDOT:PSS) with pre-perovskite deposition and dimethylsulfoxide (DMSO) rinse. The scanning electron microscope (SEM) and atomic force microscope (AFM) images confirmed a perovskite active layer consisting of large crystal grains with less grain boundary area and enhanced crystallinity. The perovskite devices fabricated by this method feature a high power conversion efficiency (PCE) of 11.36% and a short-circuit current (J) of 21.9 mAcm-2.

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