-transparent.png){kind=logo}
Herein we report the manganese-catalyzed C-C bond-forming reactions via α-alkylation of ketones, amides, and esters, using primary alcohols. β-Alkylation of secondary alcohols by primary alcohols to obtain α-alkylated ketones is also reported. The reactions are catalyzed by a ( Pr-PNP)Mn(H)(CO)2 pincer complex under mild conditions in the presence of (catalytic) base liberating water (and H2 in the case of secondary alcohol alkylation) as the sole byproduct.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
October 2016,
Organic & biomolecular chemistry,
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
January 2024,
Dalton transactions (Cambridge, England : 2003),
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
November 2015,
Angewandte Chemie (International ed. in English),
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
October 2020,
Organic letters,
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
May 2019,
Organic letters,
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
March 2017,
Organic letters,
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
September 2019,
The Journal of organic chemistry,
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
November 2016,
Angewandte Chemie (International ed. in English),
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
November 2018,
ChemSusChem,
Subrata Chakraborty, and
Prosenjit Daw, and
Yehoshoa Ben David, and
David Milstein
December 2018,
Organic letters,
