-transparent.png){kind=logo}
Gas-phase reaction of 1,3-dithiolane-2-thione over molybdenum trioxide supported on pumice stone results in efficient conversion into 1,3-dithiolan-2-one. The solid reagent is regenerated on exposure to air and thus acts as a catalyst for the overall conversion of the thione and oxygen from the air into the ketone and sulfur dioxide. The process can be carried out under either dynamic vacuum or atmospheric pressure flow conditions and using a solid reagent prepared either by physical mixing of MoO3 with the support or by solution impregnation, with an isolated yield of up to 67% obtained.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
January 1991,
Drug metabolism and disposition: the biological fate of chemicals,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
September 2009,
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
November 2003,
Acta crystallographica. Section C, Crystal structure communications,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
June 2005,
Acta crystallographica. Section C, Crystal structure communications,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
August 2012,
Acta crystallographica. Section E, Structure reports online,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
January 1990,
Drugs under experimental and clinical research,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
July 2001,
Acta crystallographica. Section C, Crystal structure communications,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
January 2023,
Acta crystallographica. Section E, Crystallographic communications,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
November 2010,
Acta crystallographica. Section E, Structure reports online,
R Alan Aitken, and
Thomasine E Curzon, and
Matthew J Andrews
June 2012,
Acta crystallographica. Section E, Structure reports online,
