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Supramolecular Light-Harvesting Antennas of Metal-Coordinated Bis(8-Hydroxyquinoline)-Substituted Porphyrin Networks. 2019
Junko Fujimoto, and
Sari Hayashi, and
Hideyuki Kainuma, and
Kazuhiro Manseki, and
Taro Udagawa, and
Hidekazu Miyaji
Biomolecular Science Course, Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan.
Artificial antenna complexes of metal-coordinated bis(8-hydroxyquinoline)-substituted porphyrin networks that mimic antenna chromophores in plants were organized on titanium dioxide electrodes in photoelectrochemical cells. The generated photocurrents can be optimized according to the two ways of porphyrin self-assembly due to the "antenna effect": changing the number of assembled porphyrin monolayers and the number of generations of the metal-coordinated porphyrin networks.
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