BIOMAT Database Logo BIOMAT Database Logo

Metal-Organic Framework with Rich Accessible Nitrogen Sites for Highly Efficient CO2 Capture and Separation. 2019

Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science , Fujian Normal University , 32 Shangsan Road , Fuzhou 350007 , P. R. China.

A novel microporous metal-organic framework (FJU-44), with abundant accessible nitrogen sites on its internal surface, was constructed from the tetrapodal tetrazole ligand tetrakis(4-tetrazolylphenyl)ethylene (H4TTPE) and copper chloride. Notably, the CO2 uptake capacity (83.4 cm3/g, at 273 K and 1 bar) in the activated FJU-44a is higher than most of tetrazolate-containing MOF materials. Particularly, FJU-44a exhibits superior adsorption selectivity of CO2/N2 (278-128) and CO2/CH4 (44-16), which is comparable to some well-known CO2 capture materials. Furthermore, the fixed-bed breakthrough experiment indicates that the postcombustion flue gas flow over a packed column with FJU-44a adsorbents can be effectively separated.

UI MeSH Term Description Entries

Related Publications

Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
A metal-organic framework with rich accessible nitrogen sites for rapid dye adsorption and highly efficient dehydrogenation of formic acid.
June 2022, Dalton transactions (Cambridge, England : 2003),
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
CO2 controls the oriented growth of metal-organic framework with highly accessible active sites.
March 2020, Nature communications,
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
Mixed Metal-Organic Framework with Multiple Binding Sites for Efficient C2 H2 /CO2 Separation.
March 2020, Angewandte Chemie (International ed. in English),
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
Metal-organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture?
April 2015, Chemical Society reviews,
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
Highly Efficient I2 Sorption, CO2 Capture, and Catalytic Conversion by Introducing Nitrogen Donor Sites in a Microporous Co(II)-Based Metal-Organic Framework.
May 2022, Inorganic chemistry,
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
Synergistic Nitrogen Binding Sites in a Metal-Organic Framework for Efficient N2 /O2 Separation.
December 2023, Angewandte Chemie (International ed. in English),
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
A Highly Stable Triazole-Functionalized Metal-Organic Framework Integrated with Exposed Metal Sites for Selective CO2 Capture and Conversion.
February 2020, Chemistry (Weinheim an der Bergstrasse, Germany),
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites.
December 2009, Proceedings of the National Academy of Sciences of the United States of America,
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
A 2-Fold Interpenetrated Nitrogen-Rich Metal-Organic Framework: Dye Adsorption and CO2 Capture and Conversion.
March 2021, Inorganic chemistry,
Yingxiang Ye, and Heng Zhang, and Liangji Chen, and Shimin Chen, and Quanjie Lin, and Fangfang Wei, and Zhangjing Zhang, and Shengchang Xiang
A highly porous metal-organic framework for large organic molecule capture and chromatographic separation.
March 2017, Chemical communications (Cambridge, England),
Copied contents to your clipboard!