Large volume liquid state scalar Overhauser dynamic nuclear polarization at high magnetic field. 2019

Thierry Dubroca, and Sungsool Wi, and Johan van Tol, and Lucio Frydman, and Stephen Hill
NHMFL, 1800 E. Paul Dirac Dr, Tallahassee, FL 32310, USA. dubroca@magnet.fsu.edu.

Dynamic Nuclear Polarization (DNP) can increase the sensitivity of Nuclear Magnetic Resonance (NMR), but it is challenging in the liquid state at high magnetic fields. In this study we demonstrate significant enhancements of NMR signals (up to 70 on 13C) in the liquid state by scalar Overhauser DNP at 14.1 T, with high resolution (∼0.1 ppm) and relatively large sample volume (∼100 μL).

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