Crystal structure of two N'-(1-phenyl-benzyl-idene)-2-(thio-phen-3-yl)acetohydrazides. 2019

Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
Faculty of Chemistry, Hanoi National University of Education, 136 Xuan Thuy, Cau Giay, Hanoi, Vietnam.

The synthesis, spectroscopic data, crystal and mol-ecular structures of two N'-(1-phenyl-benzyl-idene)-2-(thio-phen-3-yl)acetohydrazides, namely N'-[1-(4-hy-droxy-phen-yl)benzyl-idene]-2-(thio-phen-3-yl)acetohydrazide, C13H10N2O2S, (3a), and N'-[1-(4-meth-oxy-phen-yl)benzyl-idene]-2-(thio-phen-3-yl)acetohydrazide, C14H14N2O2S, (3b), are described. Both compounds differ in the substituent at the para position of the phenyl ring: -OH for (3a) and -OCH3 for (3b). In (3a), the thio-phene ring is disordered over two orientations with occupancies of 0.762 (3) and 0.238 (3). The configuration about the C=N bond is E. The thio-phene and phenyl rings are inclined by 84.0 (3) and 87.0 (9)° for the major- and minor-occupancy disorder components in (3a), and by 85.89 (12)° in (3b). Although these dihedral angles are similar, the conformation of the linker between the two rings is different [the C-C-C-N torsion angle is -ac for (3a) and -sc for (3b), while the C6-C7-N9-N10 torsion angle is +ap for (3a) and -sp for (3b)]. A common feature in the crystal packing of (3a) and (3b) is the presence of N-H⋯O hydrogen bonds, resulting in the formation of chains of mol-ecules running along the b-axis direction in the case of (3a), or inversion dimers for (3b). The most prominent contributions to the surface contacts are those in which H atoms are involved, as confirmed by an analysis of the Hirshfeld surface.

UI MeSH Term Description Entries

Related Publications

Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
March 2012, Acta crystallographica. Section E, Structure reports online,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
November 2017, Acta crystallographica. Section E, Crystallographic communications,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
September 2014, Acta crystallographica. Section E, Structure reports online,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
July 2015, Acta crystallographica. Section E, Crystallographic communications,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
March 2015, Acta crystallographica. Section E, Crystallographic communications,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
November 2012, Acta crystallographica. Section E, Structure reports online,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
August 2016, Acta crystallographica. Section E, Crystallographic communications,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
April 2011, Acta crystallographica. Section E, Structure reports online,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
October 2015, Acta crystallographica. Section E, Crystallographic communications,
Trung Vu Quoc, and Linh Nguyen Ngoc, and Duong Tran Thi Thuy, and Manh Vu Quoc, and Thien Vuong Nguyen, and Yen Oanh Doan Thi, and Luc Van Meervelt
September 2014, Acta crystallographica. Section E, Structure reports online,
Copied contents to your clipboard!