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Photoinduced Hydroxylation of Organic Halides under Mild Conditions. 2019
Yue-Ming Cai, and
Yu-Ting Xu, and
Xin Zhang, and
Wen-Xia Gao, and
Xiao-Bo Huang, and
Yun-Bing Zhou, and
Miao-Chang Liu, and
Hua-Yue Wu
College of Chemistry and Materials Engineering , Wenzhou University , Wenzhou 325035 , People's Republic of China.
Presented in this paper is photoinduced hydroxylation of organic halides, providing a mild access to a range of functionalized phenols and aliphatic alcohols. These reactions generally proceed under mild reaction conditions with no need for a photocatalyst or a strong base and show a wide substrate scope as well as excellent functional group tolerance. This work highlights the unique role of NaI that allows a challenging transformation to proceed under mild reaction conditions.
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