Modulation of crystal water in cobalt phosphate for promoted water oxidation. 2020

Jindi Qi, and Junfeng Xie, and Zimeng Wei, and Shanshan Lou, and Pin Hao, and Fengcai Lei, and Bo Tang
College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes (Ministry of Education), Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Institute of Molecular and Nano Science, Shandong Normal University, Jinan, Shandong 250014, P. R. China. xiejf@sdnu.edu.cn tangb@sdnu.edu.cn.

Herein, low-dimensional cobalt phosphate (Co-Pi) catalysts with variable contents of crystal water were fabricated for oxygen evolution reaction (OER). Owing to the optimized electronic structure, rich surface sites and favorable charge transport ability, Co-Pi tetrahydrate exhibits remarkable OER activity with a low overpotential, large current density and high intrinsic activity, and it is proved to be the optimal Co-Pi phase for OER.

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