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Coordination polymers of alkali metal cyclosiloxazanides with one- and two-dimensional structures. 2020
Maximilian Jost, and
Roman-Malte Richter, and
Markus Balmer, and
Bertram Peters, and
Fabian Dankert, and
Carsten von Hänisch
Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany. haenisch@chemie.uni-marburg.de.
The reaction of O(Si2Me4Cl)2 with ammonia yielded the cyclic siloxazane O(Si2Me4)2NH (1), which was used as a precursor for the synthesis of siloxazanide-type alkali metal salts. The metalation of 1 with the strong bases BzA (A = Na, K, Rb, Cs and Bz = benzyl) results in different dimensional structures depending on the alkali metal ion used. These results give new insights into framework design with inorganic building blocks and the coordination ability of siloxanes.
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