Effects of silylated starch structure on hydrophobization and mechanical properties of thermoplastic starch foams made from potato starch. 2020

Bruno Felipe Bergel, and Ludmila Leite Araujo, and André Luís Dos Santos da Silva, and Ruth Marlene Campomanes Santana
Polymeric Materials Lab, Materials Engineering Department, Federal University of Rio Grande do Sul, Av. Bento Gonçalves, 9500, P.O. Box 15090, ZC 91501-970 Porto Alegre, RS, Brazil. Electronic address: bruno.bergel@ufrgs.br.

Non-biodegradable single use packaging are a serious environmental problem as it generates large amounts of waste and is generally not recycled. These packages, especially those made of expanded polystyrene, can be replaced by thermoplastic starch foams. These foams have the advantage of being from renewable sources and biodegradable. However, this material is hydrophilic and becomes unusable when it is exposed to water. Hydrophobizing starch comes as an alternative to make the foams more resistant to contact with water. The purpose of the modification is to exchange starch hydroxyl groups for less polar groups such as silane groups. In this work, two silanes were used for starch silylation: 3-chloropropyl trimethoxysilane and Methyltrimethoxysilane. The foams were made using four materials: modified starch, gelatinized starch, polyvinyl alcohol and water. Results from water absorption tests and mechanical tests show that foams absorb less water and become more resistant with the addition of silylated starch.

UI MeSH Term Description Entries
D011142 Polyvinyl Alcohol A polymer prepared from polyvinyl acetates by replacement of the acetate groups with hydroxyl groups. It is used as a pharmaceutic aid and ophthalmic lubricant as well as in the manufacture of surface coatings artificial sponges, cosmetics, and other products. Liquifilm Tears,Polyviol,Alcohol, Polyvinyl,Tears, Liquifilm
D011198 Solanum tuberosum A plant species of the genus SOLANUM, family SOLANACEAE. The starchy roots are used as food. SOLANINE is found in green parts. Potatoes,Potato,Solanum tuberosums,tuberosum, Solanum,tuberosums, Solanum
D012821 Silanes Compounds similar to hydrocarbons in which a tetravalent silicon atom replaces the carbon atom. They are very reactive, ignite in air, and form useful derivatives. Silane
D013213 Starch Any of a group of polysaccharides of the general formula (C6-H10-O5)n, composed of a long-chain polymer of glucose in the form of amylose and amylopectin. It is the chief storage form of energy reserve (carbohydrates) in plants. Amylomaize Starch,Amylum,Cornstarch,Keoflo,Starch, Amylomaize
D014867 Water A clear, odorless, tasteless liquid that is essential for most animal and plant life and is an excellent solvent for many substances. The chemical formula is hydrogen oxide (H2O). (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Hydrogen Oxide
D057927 Hydrophobic and Hydrophilic Interactions The thermodynamic interaction between a substance and WATER. Hydrophilic Interactions,Hydrophilic and Hydrophobic Interactions,Hydrophilicity,Hydrophobic Interactions,Hydrophobicity,Hydrophilic Interaction,Hydrophilicities,Hydrophobic Interaction,Hydrophobicities,Interaction, Hydrophilic,Interaction, Hydrophobic,Interactions, Hydrophilic,Interactions, Hydrophobic

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