BIOMAT Database Logo BIOMAT Database Logo

Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes. 2019

Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Indiana University, Department of Chemistry, 800 E. Kirkwood Ave. Bloomington, IN 47405.

The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported.In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the alkoxy analogs generally used in these cycloadditions.

UI MeSH Term Description Entries

Related Publications

Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes.
February 2016, Angewandte Chemie (International ed. in English),
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Au-Catalyzed Intermolecular [2+2] Cycloadditions between Chloroalkynes and Unactivated Alkenes.
May 2018, Journal of the American Chemical Society,
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
ORGANIC CHEMISTRY. Iron-catalyzed intermolecular [2+2] cycloadditions of unactivated alkenes.
August 2015, Science (New York, N.Y.),
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Catalytic enantioselective allenoate-alkene [2 + 2] cycloadditions.
March 2015, Journal of the American Chemical Society,
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Enantioselective hydroamination of unactivated terminal alkenes.
February 2022, Chem,
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Catalytic hydrotrifluoromethylation of unactivated alkenes.
February 2013, Journal of the American Chemical Society,
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Catalytic Defluoroalkylation of Trifluoromethylaromatics with Unactivated Alkenes.
January 2018, Journal of the American Chemical Society,
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Cyclobutane and cyclobutene synthesis: catalytic enantioselective [2+2] cycloadditions.
October 2015, Angewandte Chemie (International ed. in English),
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Enantioselective palladium-catalyzed diarylation of unactivated alkenes.
November 2019, Chemical communications (Cambridge, England),
Michael L Conner, and Johannes M Wiest, and M Kevin Brown
Enantioselective copper-catalyzed carboetherification of unactivated alkenes.
June 2014, Angewandte Chemie (International ed. in English),
Copied contents to your clipboard!