-transparent.png){kind=logo}
Regioselective synthesis of heterocyclic N-sulfonyl amidines from heteroaromatic thioamides and sulfonyl azides. 2020
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
TOS Department, Ural Federal University named after the first President of Russia B.N. Yeltsin, 19 Mira St., 620002 Yekaterinburg, Russia.
N-Sulfonyl amidines bearing 1,2,3-triazole, isoxazole, thiazole and pyridine substituents were successfully prepared for the first time by reactions of primary, secondary and tertiary heterocyclic thioamides with alkyl- and arylsulfonyl azides. For each type of thioamides a reliable procedure to prepare N-sulfonyl amidines in good yields was found. Reactions of 1-aryl-1,2,3-triazole-4-carbothioamides with azides were shown to be accompanied with a Dimroth rearrangement to form 1-unsubstituted 5-arylamino-1,2,3-triazole-4-N-sulfonylcarbimidamides. 2,5-Dithiocarbamoylpyridine reacts with sulfonyl azides to form a pyridine bearing two sulfonyl amidine groups.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
March 2017,
The Journal of organic chemistry,
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
June 2021,
Molecules (Basel, Switzerland),
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
March 2010,
Organic letters,
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
July 2020,
RSC advances,
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
August 2018,
The Journal of organic chemistry,
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
July 2018,
Chemical communications (Cambridge, England),
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
August 2008,
Organic letters,
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
July 2015,
Organic letters,
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
June 2011,
The Journal of organic chemistry,
Vladimir Ilkin, and
Vera Berseneva, and
Tetyana Beryozkina, and
Tatiana Glukhareva, and
Lidia Dianova, and
Wim Dehaen, and
Eugenia Seliverstova, and
Vasiliy Bakulev
January 2021,
Organic letters,
