-transparent.png){kind=logo}
An unprecedented π-electronic circuit involving an odd number of carbon atoms in a grossly warped non-planar nanographene. 2021
Institute of Computational Chemistry and Catalysis and Department of Chemistry, University of Girona, C/ M. Aurèlia Capmany, 69, 17003 Girona, Spain. miquel.sola@udg.edu.
The formation of π-aromatic circuits along a grossly warped nanographene, C80H30, containing five- and seven-membered rings inserted into a six-membered mesh, reveals global π-circuits at the edge of the backbone. Based on DFT calculations, one of the two most favorable circuits for π-electron delocalization formally has 50 π-electrons abiding by Hückel's rule, whereas the second one formally has 75 π-electrons and, remarkably, it does not follow any of the known rules of aromaticity.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
September 2013,
Nature chemistry,
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
January 1984,
Ukrainskii biokhimicheskii zhurnal (1978),
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
January 1976,
S & TA & NU. Rivista di scienza e tecnologia degli alimenti e di nutrizione umana,
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
July 2017,
Angewandte Chemie (International ed. in English),
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
December 1947,
Hoppe-Seyler's Zeitschrift fur physiologische Chemie,
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
June 2008,
Journal of molecular graphics & modelling,
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
March 1995,
FEBS letters,
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
August 2022,
Physical chemistry chemical physics : PCCP,
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
November 2019,
Angewandte Chemie (International ed. in English),
Sílvia Escayola, and
Albert Poater, and
Alvaro Muñoz-Castro, and
Miquel Solà
December 2016,
Chemical communications (Cambridge, England),
