Coconut shell derived ZnCl2 activated carbon for malachite green dye removal. 2021

R Sangeetha Piriya, and Rajamani M Jayabalakrishnan, and M Maheswari, and Kovilpillai Boomiraj, and Sadish Oumabady
Department of Environmental Sciences, Tamil Nadu Agricultural University, Coimbatore 641 003, India E-mail: jayabalphd@gmail.com.

The coconut-based agricultural wastes have gained wide attention as an alternative adsorbent for the removal of diverse pollutants from the industrial effluents. This paper presents the zinc chloride activation of adsorbent carbon and the utilization as an adsorbent for the removal of malachite green dye from aqueous solution. The characterisation of activated carbon was performed to get an insight into the adsorption mechanism. The ZnCl2 activated carbon acquired a higher specific surface area (544.66 m2 g-1) and stability (-32.6 mV). The impact of process parameters including contact time (20-220 min) and initial dye concentration (20-80 mg L-1) were evaluated on the effectiveness of activated carbon for dye removal. The results concluded that zinc chloride activated carbon showed a significant dye adsorption (39.683 mg g-1) at an initial concentration of 20 mg L-1 after 3 hours. Based on the correlation coefficient (R2), the Freundlich isotherm model (0.978-0.998) was best fitted for the experimental data followed by the intraparticle diffusion model (0.88-0.929) as the most appropriate model for malachite green dye removal. Additionally, the energy and thermogravimetric analysis portrayed the suitability of the carbon material to be used as an energy alternative to coal.

UI MeSH Term Description Entries
D007700 Kinetics The rate dynamics in chemical or physical systems.
D002606 Charcoal An amorphous form of carbon prepared from the incomplete combustion of animal or vegetable matter, e.g., wood. The activated form of charcoal is used in the treatment of poisoning. (Grant & Hackh's Chemical Dictionary, 5th ed) Activated Charcoal,Actidose,Actidose-Aqua,Adsorba,Carbomix,Charbon,CharcoAid,CharcoCaps,Charcodote,Formocarbine,Insta-Char,Kohle-Compretten,Kohle-Hevert,Kohle-Pulvis,Kohle-Tabletten Boxo-Pharm,Liqui-Char,Norit,Ultracarbon,Charcoal, Activated
D003059 Cocos A plant genus of the family ARECACEAE. It is a tropical palm tree that yields a large, edible hard-shelled fruit from which oil and fiber are also obtained. Coconut,Cocoanut,Cocos nucifera,Coco,Cocoanuts,Coconuts,Cocos nuciferas,nucifera, Cocos
D006863 Hydrogen-Ion Concentration The normality of a solution with respect to HYDROGEN ions; H+. It is related to acidity measurements in most cases by pH pH,Concentration, Hydrogen-Ion,Concentrations, Hydrogen-Ion,Hydrogen Ion Concentration,Hydrogen-Ion Concentrations
D000327 Adsorption The adhesion of gases, liquids, or dissolved solids onto a surface. It includes adsorptive phenomena of bacteria and viruses onto surfaces as well. ABSORPTION into the substance may follow but not necessarily. Adsorptions
D012394 Rosaniline Dyes Compounds that contain the triphenylmethane aniline structure found in rosaniline. Many of them have a characteristic magenta color and are used as COLORING AGENTS. Fuchsins,Magentas,Fuchsin,Triphenylmethane Aniline Compounds,Aniline Compounds, Triphenylmethane,Compounds, Triphenylmethane Aniline,Dyes, Rosaniline
D014874 Water Pollutants, Chemical Chemical compounds which pollute the water of rivers, streams, lakes, the sea, reservoirs, or other bodies of water. Chemical Water Pollutants,Landfill Leachate,Leachate, Landfill,Pollutants, Chemical Water

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