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Transition metal chemistry in synthetically viable alkaline earth complexes M(Cp)3- (M = Ca, Sr, Ba). 2021
Bin Huo, and
Rui Sun, and
Bo Jin, and
Lingfei Hu, and
Jian-Hong Bian, and
Xiao-Ling Guan, and
Caixia Yuan, and
Gang Lu, and
Yan-Bo Wu
Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Institute of Molecular Science, Shanxi University, Taiyuan 030006, People's Republic of China. wyb@sxu.edu.cn.
We predicted the stable alkaline earth complexes M(Cp)3- (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the bonding behaviour of transition metals by participating in bonding with the π orbitals of Cp ligands using their d orbitals.
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