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Palladium-Catalyzed C-H Allylation of Electron-Deficient Polyfluoroarenes with gem-Difluorinated Cyclopropanes. 2021
Ping-Xin Zhou, and
Xiaozhe Yang, and
Jia Wang, and
Chunpo Ge, and
Wang Feng, and
Yong-Min Liang, and
Yu Zhang
School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, 453000, P. R. China.
A palladium-catalyzed C-H allylation of electron-deficient polyfluoroarenes with gem-difluorinated cyclopropanes is reported. It provides a useful and facile approach to 2-fluoroallylic polyfluoroarenes in moderate to excellent yields with high Z-selectivity. In addition, this new approach has good functional group compatibility and broad substrate scope.
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