Entropy production and Onsager reciprocal relations describing the relaxation to equilibrium in stochastic thermodynamics. 2021

Stefano Giordano
Univ. Lille, CNRS, Centrale Lille, Univ. Polytechnique Hauts-de-France, UMR 8520 - IEMN - Institut d'Électronique de Microélectronique et de Nanotechnologie, LIA LICS/LEMAC, F-59000 Lille, France.

We study the relation between stochastic thermodynamics and nonequilibrium thermodynamics by evaluating the entropy production and the relation between fluxes and forces in a harmonic system with N particles in contact with N different reservoirs. We suppose that the system is in a nonequilibrium stationary state in a first phase and we study the relaxation to equilibrium in a second phase. During this relaxation, we can identify the linear relation between fluxes and forces satisfying the Onsager reciprocity and we obtain a nonlinear expression for the entropy production. Only when forces and fluxes are small does the entropic production turn into a quadratic form in the forces, as predicted by the Onsager theory.

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