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Emergence of a thorium-organic framework as a radiation attenuator for selective X-ray dosimetry. 2021
Zhaofa Zheng, and
Huangjie Lu, and
Xiaofeng Guo, and
Zhengyang Zhou, and
Yumin Wang, and
Zi-Jian Li, and
Guo-Ping Xiao, and
Yuan Qian, and
Jian Lin, and
Jian-Qiang Wang
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 2019 Jia Luo Road, Shanghai 201800, China. wangjianqiang@sinap.ac.cn linjian@sinap.ac.cn.
By first applying a thorium-organic framework (Th-SINAP-2) as a radiation attenuator and by incorporating a terpyridine derivative (Htpbz) as a photo-responsive guest, selective photochromism in response to X-rays was achieved in the host-guest assembly of Htpbz@Th-SINAP-2. Such a combination endows the afforded material with the lowest detection limit of X-ray dose among all photochromic sensors and a brand-new function of X-ray dosimetry for thorium containing materials.
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