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Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production. 2021
Key Laboratory of Biobased Polymer Materials, Shandong Provincial Education Department, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
Developing visible-light-active porous organic polymers with high photocatalytic efficiency is highly desirable. Here, two triazine-based conjugated microporous polymers were synthesized. The structures were controllably adjusted to explore the structure-photocatalytic activity relationship. T-CMP-1 containing more triazine units exhibited a hydrogen evolution rate of 3214.3 μmol h-1 g-1, much higher than that of T-CMP-2 (242.1 μmol h-1 g-1). The increasing contents of triazine units bring better hydrogen evolution efficiency.
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