-transparent.png){kind=logo}
We describe here the coupling to transform aryl phosphine derivatives by the cleavage of unactivated C(aryl)-P bonds with chromium catalysis, allowing us to achieve the reaction with alkyl bromides and arylmagnesium reagents under mild conditions. Mechanistic studies indicate that catalytic cleavage of unactivated C(aryl)-P bonds is due to the in situ formed reactive Cr, followed by transmetalation and coupling with alkyl bromides.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
July 2020,
Journal of the American Chemical Society,
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
April 2020,
Journal of the American Chemical Society,
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
September 2015,
Chemical reviews,
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
July 2018,
Organic letters,
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
February 2012,
Nature,
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
January 2019,
Nature chemistry,
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
April 2010,
Angewandte Chemie (International ed. in English),
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
September 2019,
Organic letters,
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
March 2021,
Organic letters,
Jinghua Tang, and
Liang Ling, and
Shuqing Yuan, and
Meiming Luo, and
Xiaoming Zeng
February 2021,
Organic letters,
