Exciton-Phonon Coupling of Chiral One-Dimensional Lead-Free Hybrid Metal Halides at Room Temperature. 2022

Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, P. R. China.

The interaction between organic cations and inorganic metal halide octahedral units strongly affects the properties of organic-inorganic hybrid metal halides. The "soft" property of the lattice provides the possibility of its strong exciton-phonon interaction. Here we report one-dimensional (1D) lead-free chiral organic-inorganic hybrid metal halide single crystals of (R/S)-methylbenzylamine bismuth iodide (R/S-MBA)2Bi2I8, which exhibits a high level of octahedral bond distortion. The introduction of chiral amines leads to a strong chiroptical response in the range of 200-600 nm. The strong exciton-phonon coupling can be observed through the coherent oscillation spectrum of transient absorption dynamics at room temperature. The coherent phonon oscillation frequencies are ∼97 and ∼130 cm-1, corresponding to the symmetrical stretching or bending of the Bi-I octahedron. Our work provides new insights for the study of exciton-phonon coupling in 1D chiral hybrid metal halides.

UI MeSH Term Description Entries

Related Publications

Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
July 2021, Advanced science (Weinheim, Baden-Wurttemberg, Germany),
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
February 2021, Nature communications,
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
March 2024, Nano letters,
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
May 2023, The journal of physical chemistry letters,
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
September 2019, The journal of physical chemistry letters,
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
February 2022, The journal of physical chemistry letters,
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
October 2019, Inorganic chemistry,
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
August 2019, Journal of the American Chemical Society,
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
July 2019, Chemistry, an Asian journal,
Zhen Li, and Yan Yan, and Mu-Sen Song, and Jia-Yu Xin, and Hai-Yu Wang, and Hai Wang, and Yu Wang
May 2024, Physical chemistry chemical physics : PCCP,
Copied contents to your clipboard!