BIOMAT Database Logo BIOMAT Database Logo

Efficient and sustainable laccase-catalyzed iodination of p-substituted phenols using KI as iodine source and aerial O2 as oxidant. 2019

Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Bioorganische Chemie, Institut für Chemie, Universität Hohenheim Garbenstr. 30 Stuttgart D-70599 Germany ubeifuss@uni-hohenheim.de +49 711 459 22951 +49 711 459 22171.

The laccase-catalyzed iodination of p-hydroxyarylcarbonyl- and p-hydroxyarylcarboxylic acid derivatives using KI as iodine source and aerial oxygen as the oxidant delivers the corresponding iodophenols in a highly efficient and sustainable manner with yields up to 93% on a preparative scale under mild reaction conditions.

UI MeSH Term Description Entries

Related Publications

Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Thermostable bacterial laccase for sustainable dyeing using plant phenols.
June 2022, RSC advances,
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Pd(II)-catalyzed C-H iodination using molecular I2 as the sole oxidant.
July 2013, Journal of the American Chemical Society,
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Iodine-catalyzed sulfenylation of pyrazolones using dimethyl sulfoxide as an oxidant.
June 2017, Organic & biomolecular chemistry,
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Iodine as a location reagent in thin-layer chromatography iodination of phenols.
February 1967, Journal of chromatography,
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
B2pin2-Mediated Palladium-Catalyzed Diacetoxylation of Aryl Alkenes with O2 as Oxygen Source and Sole Oxidant.
September 2018, Organic letters,
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
An efficient ketone-catalyzed epoxidation using hydrogen peroxide as oxidant.
December 2000, The Journal of organic chemistry,
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Hypervalent iodine catalyzed Hofmann rearrangement of carboxamides using oxone as terminal oxidant.
December 2012, The Journal of organic chemistry,
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Protection of wood from microorganisms by laccase-catalyzed iodination.
October 2012, Applied and environmental microbiology,
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Oxovanadium(v)-catalyzed oxidative cross-coupling of enolates using O2 as a terminal oxidant.
October 2020, Chemical communications (Cambridge, England),
Mark Sdahl, and Jürgen Conrad, and Christina Braunberger, and Uwe Beifuss
Cu(II)-catalyzed functionalizations of aryl C-H bonds using O2 as an oxidant.
May 2006, Journal of the American Chemical Society,
Copied contents to your clipboard!