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Water-soluble lanthanide coordination polymers particles with white-light emission and color tuning. 2019
Kaiqi Fan, and
Xiaobo Wang, and
Yongpeng Ma, and
Yu Li, and
Guanglu Han, and
Zhigang Yin, and
Jian Song
School of Material and Chemical Engineering, Zhengzhou University of Light Industry Zhengzhou 450002 P. R. China.
Water-soluble polymer particles (PPs) with strong fluorescence emission were prepared from hyperbranched poly(ethylenimine) (PEI) and terpyridine-bearing aldehyde (TPy) via Schiff base reaction and self-assembly in aqueous phase. TPy/PEI PPs were then used to develop a series of luminescent lanthanide coordination polymers particles (Ln-CPPs). The optical properties of these Ln-CPPs are readily modulated over a wide spectrum in water systems. Finally, water-soluble white-emitting Ln-CPPs were achieved by controlling the lanthanide ion stoichiometry. This Ln-CPPs design approach offers a robust pathway for white-luminescent materials in water systems.
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