Contact Line Catch Up by Growing Ice Crystals. 2022

Rodolphe Grivet, and Antoine Monier, and Axel Huerre, and Christophe Josserand, and Thomas Séon
Laboratoire d'Hydrodynamique (LadHyX), UMR 7646 CNRS-Ecole Polytechnique, IP Paris, 91128 Palaiseau, France.

The effect of freezing on contact line motion is a scientific challenge in the understanding of the solidification of capillary flows. In this Letter, we experimentally investigate the spreading and freezing of a water droplet on a cold substrate. We demonstrate that solidification stops the spreading because the ice crystals catch up with the advancing contact line. Indeed, we observe the formation and growth of ice crystals along the substrate during the drop spreading, and show that their velocity equals the contact line velocity when the drop stops. Modeling the growth of the crystals, we predict the shape of the crystal front and show that the substrate thermal properties play a major role on the frozen drop radius.

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