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Copper-Catalyzed Regio- and Stereoselective Sulfonylation of Alkynyl Imines with Sulfonyl Hydrazides: Access to (E)-β-Sulfonyl Enones. 2022
Rongxiang Chen, and
Shaozhu Li, and
Jinju Zhang, and
Jing Cao, and
Kai-Kai Wang, and
Tuanjie Meng, and
Lantao Liu
School of Pharmacy, Xinxiang University, Xinxiang 453003, PR China.
A copper-catalyzed sulfonylation of alkynyl imines with sulfonyl hydrazides has been developed, which exhibited excellent regio- and stereoselectivity and furnished a series of (E)-β-sulfonyl enones in moderate to good yields. Mechanistic studies suggest that this strategy goes through a radical process.
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