BIOMAT Database Logo BIOMAT Database Logo

Polyoxovanadate-Based Cyclomatrix Polyphosphazene Microspheres as Efficient Heterogeneous Catalysts for the Selective Oxidation and Desulfurization of Sulfides. 2022

Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
Department of Chemistry, School of Chemistry and Chemical Engineering, Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Northwestern Polytechnical University, Xi'an 710129, China.

The [V6O13]2- cluster is successfully immobilized to the polymeric framework of cyclomatrix polyphosphazene via the facile precipitation polymerization between the phenol group symmetrically modified [V6O13]2- and hexachlorocyclotriphosphazene. The structure of the as-prepared polyoxometalate-containing polyphosphazene (HCCP-V) was characterized by FT-IR, XPS, TGA, BET, as well as SEM and zeta potential. The presence of a rigid polyoxometalate cluster not only supports the porous structure of the polymeric framework but also provides an improved catalytic oxidation property. By using H2O2 as an oxidant, the as-prepared HCCP-V exhibited improved catalytic oxidation activity toward MPS, DBT, and CEES, which can achieve as high as 99% conversion. More importantly, the immobilization of POMs in the network of cyclomatrix polyphosphazene also provides better recyclability and stability of the heterogeneous catalyst.

UI MeSH Term Description Entries
D002384 Catalysis The facilitation of a chemical reaction by material (catalyst) that is not consumed by the reaction. Catalyses
D006861 Hydrogen Peroxide A strong oxidizing agent used in aqueous solution as a ripening agent, bleach, and topical anti-infective. It is relatively unstable and solutions deteriorate over time unless stabilized by the addition of acetanilide or similar organic materials. Hydrogen Peroxide (H2O2),Hydroperoxide,Oxydol,Perhydrol,Superoxol,Peroxide, Hydrogen
D013440 Sulfides Chemical groups containing the covalent sulfur bonds -S-. The sulfur atom can be bound to inorganic or organic moieties. Sulfide,Thioether,Thioethers,Sulfur Ethers,Ethers, Sulfur
D017550 Spectroscopy, Fourier Transform Infrared A spectroscopic technique in which a range of wavelengths is presented simultaneously with an interferometer and the spectrum is mathematically derived from the pattern thus obtained. FTIR,Fourier Transform Infrared Spectroscopy,Spectroscopy, Infrared, Fourier Transform

Related Publications

Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
Polyphosphazene-Functionalized Microspheres as Efficient Catalysts for the Knoevenagel Reaction under Mild Conditions.
November 2022, ChemPlusChem,
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
In Situ Ligand-Transformation-Involved Synthesis of Inorganic-Organic Hybrid Polyoxovanadates as Efficient Heterogeneous Catalysts for the Selective Oxidation of Sulfides.
December 2020, Inorganic chemistry,
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
Synthesis of Negative-Charged Metal-Containing Cyclomatrix Polyphosphazene Microspheres Based on Polyoxometalates and Application in Charge-Selective Dye Adsorption.
September 2019, Macromolecular rapid communications,
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
One-Pot Synthesis of Cyclomatrix-Type Polyphosphazene Microspheres and Their High Thermal Stability.
March 2023, ACS omega,
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
Copper-Containing Polyoxometalate-Based Metal-Organic Frameworks as Highly Efficient Heterogeneous Catalysts toward Selective Oxidation of Alkylbenzenes.
December 2019, Inorganic chemistry,
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
A Polyoxovanadate-Resorcin[4]arene-Based Porous Metal-Organic Framework as an Efficient Multifunctional Catalyst for the Cycloaddition of CO2 with Epoxides and the Selective Oxidation of Sulfides.
October 2017, Inorganic chemistry,
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
Magneli-type tungsten oxide nanorods as catalysts for the selective oxidation of organic sulfides.
October 2021, Dalton transactions (Cambridge, England : 2003),
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
Superhydrophobic materials as efficient catalysts for hydrocarbon selective oxidation.
January 2011, Chemical communications (Cambridge, England),
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
Assembly of polyoxometalate-thiacalix[4]arene-based inorganic-organic hybrids as efficient catalytic oxidation desulfurization catalysts.
February 2021, Dalton transactions (Cambridge, England : 2003),
Yinghui Hu, and Diping Huang, and Jing Yan, and Zhiliang Miao, and Lize Yu, and Ningjing Cai, and Quanhai Fang, and Qiuyu Zhang, and Yi Yan
Four metalloporphyrinic frameworks as heterogeneous catalysts for selective oxidation and aldol reaction.
April 2013, Inorganic chemistry,
Copied contents to your clipboard!