Functionalization of the Implant Surface Made of NiTi Shape Memory Alloy. 2023

Karolina Dudek, and Tomasz Goryczka, and Mateusz Dulski, and Bronisław Psiuk, and Agnieszka Szurko, and Zdzisław Lekston
Center of Refractory Materials, Łukasiewicz Research Network-Institute of Ceramics and Building Materials, Toszecka 99, 44-100 Gliwice, Poland.

To functionalize and improve the biocompatibility of the surface of a medical implant made of NiTi shape memory alloy and used in practice, a clamp, multifunctional layers composed of amorphous TiO2 interlayer, and a hydroxyapatite coating were produced. Electrophoresis, as an efficient method of surface modification, resulted in the formation of a uniform coating under a voltage of 60 V and deposition time of 30 s over the entire volume of the implant. The applied heat treatment (800 °C/2 h) let toa dense, crack-free, well-adhered HAp coating with a thickness of ca. 1.5 μm. and a high crack resistance to deformation associated with the induction of the shape memory effect in the in the deformation range similar to the real implant work after implantation. Moreover, the obtained coating featured a hydrophilic (CA = 59.4 ± 0.3°) and high biocompatibility.

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