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Photophysical properties of tetrabutylammonium metal chlorides with different inorganic frameworks. 2023

Qichuan Hu, and Jing Liu, and Hailong Yu, and Hanqi Xu, and Jinyang Yu, and Wenzhi Wu
School of Electronic Engineering, Heilongjiang University, Harbin, Heilongjiang, 150080, China. wuwenzhi@hlju.edu.cn.

The luminescence of single crystals of (TBA)PbCl3, (TBA)2Sb2Cl8, (TBA)3Bi2Cl9 and (TBA)SnCl5·2EtOH (TBA = tetrabutylammonium, EtOH = Ethanol) synthsized were assigned distinctively to the centres of self-trapped excitons (STEs), TBA+, TBA+ and co-emission of STEs and TBA+. This work demonstrates that organic cations without benzene or aromatic rings can also be used as the sole luminescence centres for metal halides.

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