Biomaterial Database

Effect of preheating on mechanical properties of a resin-based composite containing elastomeric urethane monomer. 2023

João Marcos Nascimento Batista, and Mário Alexandre Coelho Sinhoreti, and May Anny Alves Fraga, and Marcus Vinícius Manoel da Silva, and Américo Bortolazzo Correr, and Jean-François Roulet, and Saulo Geraldeli

Department of Restorative Dentistry, Dental Materials Division, Piracicaba Dental School, University of Campinas, Piracicaba, SP, Brazil.

This study investigated the effect of preheating an elastomeric urethane monomer (Exothane-24) experimental resin composite on its physicochemical properties. Two resin matrices were formulated: (a) 50 wt% Bisphenol-glycidyl methacrylate (Bis-GMA) and 50 wt% triethylene glycol dimethacrylate (TEGDMA); and (b) 20 wt% Exothane-24, 40 wt% Bis-GMA and 40 wt% TEGDMA. A photoinitiator system (0.25 wt% camphorquinone and 0.50 wt% ethyl-4-dimethylamino benzoate) and 65 wt% of the inorganic filler (20 wt% 0.05 μm silica and 80 wt% 0.7 μm BaBSiO2 glass) were added to both matrices. These formulations were then assigned to four groups: Exothane-24 (E); Exothane-24 plus preheating (EH); no Exothane-24 (NE); and no Exothane-24 plus preheating (NEH). NEH and EH were preheated at 69 °C. The dependent variables were as follows: film thickness (FT); polymerization shrinkage stress (PSS); gap width (GW); maximum rate of polymerization (Rpmax); and degree of conversion (DC). Data were statistically analyzed by two-way ANOVA and Tukey's test (α = 0.05). Preheating reduced FT for both composites. PSS and GW were significantly lower for EH, when compared with E. The DC for EH and NEH and the Rpmax for EH increased significantly. Preheating improved most of the physicochemical properties (FT, PSS, GW, and DC) of the experimental resin composite containing Exothane-24.

UI	MeSH Term	Description	Entries
D008422	Materials Testing	The testing of materials and devices, especially those used for PROSTHESES AND IMPLANTS; SUTURES; TISSUE ADHESIVES; etc., for hardness, strength, durability, safety, efficacy, and biocompatibility.	Biocompatibility Testing,Biocompatible Materials Testing,Hemocompatibility Testing,Testing, Biocompatible Materials,Testing, Hemocompatible Materials,Hemocompatibility Testings,Hemocompatible Materials Testing,Materials Testing, Biocompatible,Materials Testing, Hemocompatible,Testing, Biocompatibility,Testing, Hemocompatibility,Testing, Materials,Testings, Biocompatibility
D008689	Methacrylates	Acrylic acids or acrylates which are substituted in the C-2 position with a methyl group.	Methacrylate
D011092	Polyethylene Glycols	Polymers of ETHYLENE OXIDE and water, and their ethers. They vary in consistency from liquid to solid depending on the molecular weight indicated by a number following the name. They are used as SURFACTANTS, dispersing agents, solvents, ointment and suppository bases, vehicles, and tablet excipients. Some specific groups are NONOXYNOLS, OCTOXYNOLS, and POLOXAMERS.	Macrogols,Polyoxyethylenes,Carbowax,Macrogol,Polyethylene Glycol,Polyethylene Oxide,Polyethyleneoxide,Polyglycol,Glycol, Polyethylene,Glycols, Polyethylene,Oxide, Polyethylene,Oxides, Polyethylene,Polyethylene Oxides,Polyethyleneoxides,Polyglycols,Polyoxyethylene
D011109	Polymethacrylic Acids	Poly-2-methylpropenoic acids. Used in the manufacture of methacrylate resins and plastics in the form of pellets and granules, as absorbent for biological materials and as filters; also as biological membranes and as hydrogens. Synonyms: methylacrylate polymer; poly(methylacrylate); acrylic acid methyl ester polymer.	Methacrylic Acid Polymers,Acid Polymers, Methacrylic,Acids, Polymethacrylic,Polymers, Methacrylic Acid
D002219	Carbamates	Derivatives of carbamic acid, H2NC(	Carbamate,Aminoformic Acids,Carbamic Acids,Acids, Aminoformic,Acids, Carbamic
D003188	Composite Resins	Synthetic resins, containing an inert filler, that are widely used in dentistry.	Composite Resin,Resin, Composite,Resins, Composite
D014520	Urethane	Antineoplastic agent that is also used as a veterinary anesthetic. It has also been used as an intermediate in organic synthesis. Urethane is suspected to be a carcinogen.	Ethyl Carbamate,Urethan,Carbamate, Ethyl
D017438	Bisphenol A-Glycidyl Methacrylate	The reaction product of bisphenol A and glycidyl methacrylate that undergoes polymerization when exposed to ultraviolet light or mixed with a catalyst. It is used as a bond implant material and as the resin component of dental sealants and composite restorative materials.	Bis-GMA,Bis-GMA Polymer,2-Propenoic acid, 2-methyl-, (1-methylethylidene)bis(4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)) ester, homopolymer,Adaptic,Bis(Phenol A-Glycidyl Methacrylate),Bis(Phenol A-Glycidyl Methacrylate), Homopolymer,Bis(Phenol A-Glycydyl Methacrylate),Bis-GMA Resin,Bisphenol A-Glycidyl Methacrylate Homopolymer,Bisphenol A-Glycidyl Methacrylate Polymer,Concise Composite Resin,Concise Enamel Bond,Concise Enamel Bond System,Concise Resin,Concise White Sealant,Conclude Composite Resin,Conclude Resin,Delton,Epoxylite-9075,Kerr Pit and Fissure Sealant,Kerr Sealer,Nuva-Seal,Panavia Opaque,Poly(Bis-GMA),Retroplast,Silux,Bis GMA,Bis GMA Polymer,Bis GMA Resin,Bis-GMA Polymers,Bis-GMA Resins,Bisphenol A Glycidyl Methacrylate,Bisphenol A Glycidyl Methacrylate Homopolymer,Bisphenol A Glycidyl Methacrylate Polymer,Bond, Concise Enamel,Composite Resin, Concise,Composite Resin, Conclude,Composite Resins, Concise,Concise Composite Resins,Concise Resins,Enamel Bond, Concise,Epoxylite 9075,Epoxylite9075,Methacrylate, Bisphenol A-Glycidyl,Nuva Seal,NuvaSeal,Opaque, Panavia,Polymer, Bis-GMA,Polymers, Bis-GMA,Resin, Bis-GMA,Resin, Concise,Resin, Concise Composite,Resin, Conclude,Resin, Conclude Composite,Resins, Bis-GMA,Resins, Concise,Resins, Concise Composite
D058105	Polymerization	Chemical reaction in which monomeric components are combined to form POLYMERS (e.g., POLYMETHYLMETHACRYLATE).	Polymerizations