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[2.2]Paracyclophane Derivatives as Building Blocks for Coordination Polymers. 2023
Mihail Lucian Birsa, and
Henning Hopf, and
Peter G Jones, and
Laura Gabriela Sarbu, and
Lucian Gabriel Bahrin
Department of Chemistry, Alexandru Ioan Cuza University of Iasi, No. 11 Carol I Blvd., 700506 Iasi, Romania.
Several new di- and tetracarboxylic [2.2]paracyclophane derivatives were obtained via Suzuki coupling between the appropriately brominated [2.2]paracyclophanes and 4-(methoxycarbonyl)phenylboronic acid. The reaction of one of these products, namely pp-bis(4-carboxyphenyl)[2.2]paracylophane (12), with zinc nitrate afforded a 2D coordination polymer comprising zinc-carboxylate paddlewheel clusters linked together by cyclophane cores. The zinc center is five-coordinated in a square-pyramidal geometry, with a DMF oxygen atom at the apex and four carboxylate oxygen atoms in the base.
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