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Lipases (triacylglycerol acylhydrolase, EC 3.1.1.3) have been used in organic media for the catalysis of reactions such as hydrolysis, esterification and transesterification. In these conditions it was confirmed that all reactions proceed through an acyl enzyme intermediate in two successive steps: acyl enzyme formation and solvolysis. The competition between two acyl acceptors (acyl donors) for reaction with a donor (acceptor) is described for the first time. A kinetic model is proposed using a competitive factor which is in good accordance with experimental results. The model was used successfully for the prediction of alcohol (acid) separations and resolutions by lipases.
H Deleuze, and
G Langrand, and
H Millet, and
J Baratti, and
G Buono, and
C Triantaphylides
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H Deleuze, and
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January 1999,
Sheng wu hua xue yu sheng wu wu li xue bao Acta biochimica et biophysica Sinica,
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January 2012,
International journal of molecular sciences,
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September 2017,
Molecules (Basel, Switzerland),
H Deleuze, and
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March 2003,
Biotechnology letters,
H Deleuze, and
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January 2000,
Biotechnology progress,
H Deleuze, and
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January 2019,
Advances in biochemical engineering/biotechnology,
H Deleuze, and
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C Triantaphylides
February 2020,
Applied microbiology and biotechnology,
H Deleuze, and
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C Triantaphylides
January 2000,
Biomacromolecules,
