Photocatalytic Removal of Metronidazole Antibiotics from Water Using Novel Ag-N-SnO2 Nanohybrid Material. 2024

Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering and Technology, University of Dhaka, Dhaka 1000, Bangladesh.

In this study, we employed a straightforward synthetic approach using the sol-gel method to fabricate a novel photocatalyst, Ag and N co-doped SnO2 (Ag-N-SnO2). The synthesized photocatalysts underwent characterization through various techniques including XRD, FTIR, FESEM-EDS, TEM, UV-vis DRS, BET, and XPS. The UV-vis DRS results confirmed a reduction in the bandgap energy of Ag-N-SnO2, leading to enhanced absorption of visible light. Additionally, TEM data demonstrated a smaller particle size for Ag-N-SnO2, and BET analysis revealed a significant increase in surface area compared to SnO2.The efficiency of the Ag-N-SnO2 photocatalyst in degrading metronidazole (MNZ) under natural sunlight surpassed that of SnO2. Under optimal conditions (Ag-N-SnO2 concentration of 0.4 g/L, MNZ concentration of 10 mg/L, pH 9, and 120 min of operation), the highest MNZ photocatalytic removal reached 97.03%. The reaction kinetics followed pseudo-first-order kinetics with a rate constant of 0.026 min-1. Investigation into the mineralization of MNZ indicated a substantial decrease in total organic carbon (TOC) values, reaching around 56% in 3 h of sunlight exposure. To elucidate the photocatalytic degradation mechanism of MNZ with Ag-N-SnO2, a scavenger test was employed which revealed the dominant role of •O2-. The results demonstrated the reusability of Ag-N-SnO2 for up to four cycles, highlighting its cost-effectiveness and environmental friendliness as a photocatalyst.

UI MeSH Term Description Entries

Related Publications

Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
November 2019, Environmental research,
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
January 2016, Analytical chemistry insights,
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
October 2011, Journal of hazardous materials,
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
December 2022, Chemosphere,
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
October 2023, Environmental science and pollution research international,
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
January 2023, Materials (Basel, Switzerland),
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
November 2019, Environmental science and pollution research international,
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
January 1982, Voprosy virusologii,
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
September 2022, Chemosphere,
Md Shahriar Hossain Shuvo, and Rupna Akther Putul, and Khandker Saadat Hossain, and Shah Md Masum, and Md Ashraful Islam Molla
January 2019, MethodsX,
Copied contents to your clipboard!